Lithium Gets a Good Wrap

Dean Sigler Electric Powerplants, Sustainable Aviation Leave a Comment

Shadi Dayeh, professor in the Department of Electrical and Computer Engineering at the UC San Diego Jacobs School of Engineering, has been designing new electrode architectures that could solve one of lithium batteries’ biggest problems.  When lithium diffuses across the surface of a lithium-ion battery electrode, it causes the electrode to expand and contract depending on its charging or discharging.  This eventually leads to cracking and ultimate disintegration of the anode or cathode – weakening and finally disabling the battery. Dayeh, working with colleagues at the University and Sandia and Los Alamos National Laboratories, came up with nanowires that, “Block diffusion of lithium (Li) across their silicon surface and promote layer-by-layer axial lithiation of the nanowire’s germanium core.” Seeing possibilities beyond his current research, Dayeh says the work could lead to, “An effective way to tailor volume expansion of lithium ion battery electrodes which could potentially minimize their cracking, improve their durability, and perhaps influence how one could think about …