Caging Silicon Anodes with Graphene

Dean Sigler Announcements, Batteries, Sustainable Aviation 0 Comments

Dr. Yi Cui of Stanford University has expanded the idea of “battery” to include conductive ink on paper, fruit-like clusters of energy-storing capsules, and now, nano-sized graphene cages in which the energy can romp like a hamster in a plastic ball.  He will be on hand at this year’s Sustainable Aviation Symposium on May 6, at the Sofitel San Francisco Bay hotel. His pioneering work with silicon as an electrode material goes back at least ten years, and has focused on overcoming silicon’s two major problems in battery use.  Silicon expands and begins breaking down during repeated charge-discharge cycles.  It reacts with battery electrolyte to form a coating that progressively destroys performance.  The combination of crumbling and coating finally makes the …

Dr. Cui’s Pomegranate-inspired Battery Bears Fruit

Dean Sigler Electric Powerplants, Sustainable Aviation 0 Comments

Dr. Yi Cui seems to get inspiration from food.  A few years ago, his research team came up with a “yolk-shell structure” that helped contain the high amount of lithium that silicon anodes were able to absorb.  That battery design promised much, and an embellishment of that design seems to hold even greater promise. His newest effort, working at Stanford University with the Department of Energy’s SLAC National Accelerator Laboratory, features an electrode “designed like a pomegranate – with silicon nanoparticles clustered like seed in a tough carbon rind.”  This approach, according to its inventors, overcomes several remaining obstacles to the use of silicon in a new generation of lithium-ion batteries. Yi said the battery’s efficiency and longevity are promising.  …