ORNL and Solid Power Sign Lithium-Sulfur Agreement

Dean Sigler Batteries, Electric Powerplants, Sustainable Aviation Leave a Comment

Solid-state batteries are becoming the next big thing in energy storage, with the promise of low volatility, high energy density and lower-cost manufacturing.  With academia, industry and government collaborating on the next wave of development, we may see progress in this realm. Recently, the Department of Energy’s Oak Ridge National Laboratory and Solid Power Inc. of Louisville, Colo., signed an exclusive agreement licensing lithium-sulfur materials for next-generation batteries. A team of current and former ORNL researchers including Chengdu Liang, Nancy Dudney, Adam Rondinone, Jong Keum, Jane Howe, Wujun Fu, Ezhiylmurugan Rangasamy, Zhan Lin and Zengcai Liu developed the technology.  This included designing and testing an all-solid lithium-sulfur battery “with approximately four times the energy density of conventional lithium-ion technologies.”  It featured a “new Oak Ridge-designed sulfur-rich cathode and a lithium anode with a solid electrolyte material, also developed at ORNL.” Oak Ridge has also licensed a method of forming lithium-containing electrolytes using wet chemical synthesis, which may comprise β-Li3PS4 or Li4P2S7. Reportedly, Solid …

2X Solid State Batteries?

Dean Sigler Electric Powerplants, Sustainable Aviation Leave a Comment

Applied Materials, located in Sunnyvale, California, designs and makes equipment used in the manufacture of computer chips and other miniature electronic devices.  Your editor worked there on assignment from his engineering firm for six months 15 years ago, documenting and verifying the equipment and control systems for their newest facility.  Even then, miniature was wild understatement, with the company crafting machinery that could produce 0.18 µm lines in silicon chips.  In the last two decades, line widths have shrunk to 0.03 µm, and the number of elements on chips has increased proportionally.  This makes nano manufacturing a highly precise endeavor, and one which seems to defy credulity with lower costs for the ever-increasing number of chips being made. It’s this type of manufacturing expertise which makes possible the electronic life we lead today and one that relies increasingly on energy storage technology.  The very things that make solid state computing possible could produce solid state batteries – an advantageous storage …

My Battery Won’t Blow Up. It’s Gellin’

Dean Sigler Electric Powerplants, Sustainable Aviation Leave a Comment

We think of gel inserts as something to absorb energy in shoes, and their uses extend into saddle cushions and protective seat pads for racing drivers.  Researchers in South Korea, however, are looking at ways to transfer ions through gelatins similar to those used in Japanese food. Konnyaku is a vegan gelatin often used to make stretchy noodles popular in Japanese cooking.  A similar organic gel (organogel) can be used in electrolytes with “high ionic conductivity and cationic transference number,” according to a research team at Ulsan National Institute of Science and Technology (UNIST), South Korea. Professors Hyun-Kon Song and Noejung Park of UNIST and their fellow researchers have developed an organogel polymer electrolyte that looks like clear Jello® and which could solve problems presented by liquid electrolytes.  Their electrolyte gels irreversibly despite surrounding temperatures, and passes lithium ions easily. Stability during thermal events might have prevented recent battery fires on the Boeing 787, according to Song and Park.  The …

Solid, Man! Electrolytes Go Granular

Dean Sigler Electric Powerplants, Sustainable Aviation Leave a Comment

Most liquid battery electrolytes that conduct ions between anode and cathode also carry with them a flammability problem, especially as chemists try to pack more power into smaller batteries.  Recent fires which have grounded all Boeing 787s in the world highlight the danger. The blog has noted before the dangers of overcharging lithium batteries and especially of leaving even model airplane sized packs lying about unattended during charging. Oak Ridge National Laboratory researchers claim to have demonstrated safety advantages with a nanoporous electrolyte, according to a January 23, 2013 release.  ORNL’s Chengdu Liang says, “To make a safer, lightweight battery, we need the design at the beginning to have safety in mind.  We started with a conventional material that is highly stable in a battery system – in particular one that is compatible with a lithium metal anode.” In line with objectives set by Secretary of Energy Steven Chu, using pure lithium metal as an anode could produce batteries with …