ORNL and Solid Power Sign Lithium-Sulfur Agreement

Dean Sigler Batteries, Electric Powerplants, Sustainable Aviation Leave a Comment

Solid-state batteries are becoming the next big thing in energy storage, with the promise of low volatility, high energy density and lower-cost manufacturing.  With academia, industry and government collaborating on the next wave of development, we may see progress in this realm. Recently, the Department of Energy’s Oak Ridge National Laboratory and Solid Power Inc. of Louisville, Colo., signed an exclusive agreement licensing lithium-sulfur materials for next-generation batteries. A team of current and former ORNL researchers including Chengdu Liang, Nancy Dudney, Adam Rondinone, Jong Keum, Jane Howe, Wujun Fu, Ezhiylmurugan Rangasamy, Zhan Lin and Zengcai Liu developed the technology.  This included designing and testing an all-solid lithium-sulfur battery “with approximately four times the energy density of conventional lithium-ion technologies.”  It featured a “new Oak Ridge-designed sulfur-rich cathode and a lithium anode with a solid electrolyte material, also developed at ORNL.” Oak Ridge has also licensed a method of forming lithium-containing electrolytes using wet chemical synthesis, which may comprise β-Li3PS4 or Li4P2S7. Reportedly, Solid …

Longer Life and More Energy

Dean Sigler Electric Powerplants, Sustainable Aviation Leave a Comment

Who wouldn’t want both?  Researchers in Germany and America are making great inroads on lithium battery energy density, while  adding some hope that batteries may someday outlast the vehicle in which they are installed. Ulm, Germany, where the Berblinger Competition encourages economical flight, may be a resource for making such flight possible.  The Zentrum für Sonnenenergie- und WasserstoffForschung Baden-Württemberg (Centre for Solar Energy and Hydrogen Research Baden-Württemberg, ZSW), has announced what they claim to be world-beating cells in terms of cycle life. Dr. Margret Wohlfahrt-Mehrens, Head of the Accumulator Material Research Department in Ulm reports, “After 10,000 complete charging and discharging cycles with a complete charge and discharge cycle per hour (2 C), our lithium batteries still have more than 85 % of the initial capacity.” This would be equivalent to a full charge and discharge cycle every day for over 27 years. With active materials exclusively from Germany, the Ulm battery competes with those manufactured in Asia for power …

Solid, Man! Electrolytes Go Granular

Dean Sigler Electric Powerplants, Sustainable Aviation Leave a Comment

Most liquid battery electrolytes that conduct ions between anode and cathode also carry with them a flammability problem, especially as chemists try to pack more power into smaller batteries.  Recent fires which have grounded all Boeing 787s in the world highlight the danger. The blog has noted before the dangers of overcharging lithium batteries and especially of leaving even model airplane sized packs lying about unattended during charging. Oak Ridge National Laboratory researchers claim to have demonstrated safety advantages with a nanoporous electrolyte, according to a January 23, 2013 release.  ORNL’s Chengdu Liang says, “To make a safer, lightweight battery, we need the design at the beginning to have safety in mind.  We started with a conventional material that is highly stable in a battery system – in particular one that is compatible with a lithium metal anode.” In line with objectives set by Secretary of Energy Steven Chu, using pure lithium metal as an anode could produce batteries with …