Rice Defeats Dendrites

Dean Sigler Batteries, Electric Aircraft Materials, Sustainable Aviation Leave a Comment

Dr. James Tour of Rice University makes news regularly with different ways of making better batteries.  His latest, a thin-film coating of carbon nanotubes, will enable lithium metal batteries to potentially achieve their full potential.

Rice University chemist James Tour, left, graduate student Gladys López-Silva and postdoctoral researcher Rodrigo Salvatierra use a film of carbon nanotubes to prevent dendrite growth in lithium metal batteries, which charge faster and hold more power than current lithium-ion batteries. Photo by Jeff Fitlow

According to the Tour Laboratory, that potential is worth considering.  “Lithium metal charges much faster and holds about 10 times more energy by volume than the lithium-ion electrodes found in just about every electronic device, including cellphones and electric cars.”  This promise is offset by problems with dendrite growth, the intrusion of tooth-like projections from the surface of the anode metal.  If these growths expand far enough, they poke through the battery’s electrolyte and severely limit battery life.  Worst of all, if the dendrites reach the cathode, they short out the battery, and possibly cause thermal runaway and  fires.

Microscope images of lithium metal anodes after 500 charge/discharge cycles in tests at Rice University show the growth of dendrites is quenched in the anode at left, protected by a film of carbon nanotubes. The unprotected lithium metal anode at right shows evidence of dendrite growth. (Credit: Tour Group/Rice University)

Tour and his student researchers have found that coating the lithium metal electrodes with a thin layer of carbon nanotubes keeps dendrites under control, and allows fast charging and an extended number of charge-discharge cycles.

Tour explained a surprising aspect of the team’s solution. “What we’ve done turns out to be really easy.  You just coat a lithium metal foil with a multiwalled carbon nanotube film. The lithium dopes the nanotube film, which turns from black to red, and the film in turn diffuses the lithium ions.”

Researchers explain, “When the battery is in use, the film discharges stored ions and the underlying lithium anode refills it, maintaining the film’s ability to stop dendrite growth.”

An illustration shows how lithium metal cathodes developed at Rice University are protected from dendrite growth by a film of carbon nanotubes. (Credit: Tour Group/Rice University)

Rice postdoctoral researcher Rodrigo Salvatierra, co-lead author of the paper with graduate student Gladys López-Silva explains, “Physical contact with lithium metal reduces the nanotube film, but balances it by adding lithium ions. The ions distribute themselves throughout the nanotube film.

After stopping dendrite growth for 580 charge-discharge cycles, a sulfurized-carbon film helped the full lithium metal test cells retain 99.8 percent of their coulombic efficiency, “the measure of how well electrons move within an electrochemical system.”

Current research is just the latest in several breakthroughs announced by the school.  Last May, the Tour Laboratory announced development of a graphene nanotube hybrid lithium metal battery with three times the energy density of a conventional lithium-ion cell.  Another development, the use of asphalt, of all things, to help lithium batteries charge faster was announced last October.

Co-authors of the paper, published in Advanced Materials, are Rice alumni Almaz Jalilov of the King Fahd University of Petroleum and Minerals, Saudi Arabia; Jongwon Yoon, a senior researcher at the Korea Basic Science Institute; and Gang Wu, an instructor, and Ah-Lim Tsai, a professor of hematology, both at the McGovern Medical School at the University of Texas Health Science Center at Houston. Tour is the T.T. and W.F. Chao Chair in Chemistry as well as a professor of computer science and of materials science and nanoengineering at Rice.

The research was supported by the Air Force Office of Scientific Research, the National Institutes of Health, the National Council of Science and Technology, Mexico; the National Council for Scientific and Technological Development, Ministry of Science, Technology and Innovation and Coordination for the Improvement of Higher Education Personnel, Brazil; and Celgard, LLC.

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