Gaining an Edge for Energy Production and Storage

Dean Sigler Electric Powerplants, Sustainable Aviation Leave a Comment

Rice University scientists who want to gain an edge in energy production and storage report they have found it in molybdenum disulfide.  From Wikipedia: “Molybdenum disulfide is the inorganic compound with the formula MoS 2. The compound is classified as a metal dichalcogenide. It is a silvery black solid that occurs as the mineral molybdenite, the principal ore for molybdenum.   MoS 2 is relatively unreactive. It is unaffected by dilute acids and oxygen. In appearance and feel,molybdenum disulfide is similar to graphite. It is widely used as a solid lubricant because of its low friction properties and robustness.” Let’s break down one probably unfamiliar term (it was to your editor).  A chalogen is one of the members of the Vla group in the periodic table and includes oxygen, sulfur, selenium, tellurium, and polonium.  Add a more electropositive element to one of those and we get a chalogenide.  Double down and make it a dichalogenide, in this case a material that looks similar to graphene, but more three-dimensional, with three layers because it has slab of molybdenum sandwiched between two …

Three Battery Technologies with Great Potential

Dean Sigler Electric Powerplants, Sustainable Aviation Leave a Comment

It’s a good week when at least three battery developments show promise for electric vehicle use in the near future.  One advanced lithium-ion battery from France, a dual-carbon battery from Japan, and a supercapacitor that one can wrap around one’s finger comprise the trio. French Lithium-Tin Dioxide “Synthesizing nanoparticles of tin dioxide (SnO2) in the pores of a carbonaceous material,” researchers at the Institute of Materials Science of Mulhouse and Charles Gerhardt Institute of Montpellier, part of an electrochemical energy storage consortium called RS2E, have found the material to have “remarkable properties.”  Their work is the subject of a patent and published in the journal, Advanced Energy Materials. Researchers, hoping to obtain better performance that that achieved with carbon electrodes, tested combinations of nickel (Ni),  iron  (Fe), cobalt (Co), and other materials before hitting on tin dioxide as a material of choice.  All have (theretically) far greater electrochemical storage capacity than graphite, but expand and contract during charging and discharging of the battery, …

Unzipped Nanotubes Show Energetic Promise

Dean Sigler Electric Powerplants, Sustainable Aviation Leave a Comment

Rice University, supported by the Air Force Office of Scientific Research (AFOSR), has demonstrated “a way to boost the efficiency of the ubiquitous lithium ion (LI) battery by employing ribbons of graphene that start as carbon nanotubes.” The AFOSR explains, “Four years ago, [Rice chemist James] Tour’s research team demonstrated that they could chemically unzip cylindrical shaped carbon nanotubes into soluble graphene nanoribbons (GNR) without compromising the electronic properties of the graphitic structure. A recent paper by the Tour team, published in IEEE Spectrum and partially funded by AFOSR, showed that GNR can significantly increase the storage capacity of lithium ion (Li-ion) by combining graphene nanoribbons with tin oxide. “By producing GNR in bulk, a necessary requirement for making this a viable process, the Tour team mixes GNR and 10 nanometer wide particles of tin oxide to create a slurry. GNRs, a single atom thick and thousands of times longer than they are wide, not only separate and support the …