Caging Silicon Anodes with Graphene

Dean Sigler Announcements, Batteries, Sustainable Aviation Leave a Comment

Dr. Yi Cui of Stanford University has expanded the idea of “battery” to include conductive ink on paper, fruit-like clusters of energy-storing capsules, and now, nano-sized graphene cages in which the energy can romp like a hamster in a plastic ball.  He will be on hand at this year’s Sustainable Aviation Symposium on May 6, at the Sofitel San Francisco Bay hotel. His pioneering work with silicon as an electrode material goes back at least ten years, and has focused on overcoming silicon’s two major problems in battery use.  Silicon expands and begins breaking down during repeated charge-discharge cycles.  It reacts with battery electrolyte to form a coating that progressively destroys performance.  The combination of crumbling and coating finally makes the battery inoperable. His group at Stanford had found a way to “wrap every silicon anode particle in a custom-fit cage made of graphene, a pure form of carbon that is the thinnest and strongest material known and a great conductor …

Samsung Almost Doubles Li-Ion Battery Capacity – in the Near Future

Dean Sigler Electric Powerplants, Sustainable Aviation Leave a Comment

Several sources report on Samsung’s announcement that they have developed a new technology that enables them to coat silicon battery cathodes with high crystal graphene, virtually doubling the capacity of lithium-ion batteries. Of course, Samsung relates this immediately to their popular smartphones and tablets, but the significance of this is not lost on electric vehicle designers.  Doubling the range of EVs “without adding a single pound of weight” would be a true game changer.  But don’t get excited too quickly. Silicon electrodes have been a major research effort for people like Dr. Yi Cui, who spoke at this year’s Electric Aircraft Symposium.  Issue surrounding their successful use have included silicon’s expansion when being charged and contraction when being discharged.  This errant flexibility causes eventual disintegration of the electrodes and shuts down the battery.  Attempts to use silicon nanowires still have led to embrittlement. Kompulsa.com reports Cho Jin-young from BusinessKorea explaining, “Currently, the development of high-capacity battery materials has been mostly done …