Vanadium Oxide/Lithium Batteries Offer Promise of High Power, Long Life

Dean Sigler Electric Powerplants, Sustainable Aviation Leave a Comment

Henry Ford once brought a French metallurgist to Detroit, part of his plan to build cars with lighter, stronger steel.  Vanadium, which the French used in their automobiles, offered him the chance to make the Model T lighter and stronger, and its part in the car’s alloyed steel gave the Model T the longevity which followed it through one of the longest production runs in history. Now battery researchers are looking at another quality of this mineral, its ability to form a superior cathode for batteries that “could supply both high energy density and significant power density.   Combined with graphene, the wonder material du jour, vanadium oxide (VO2) could couple longevity echoing the Model T’s with charge and discharge rapidity similar to a supercapacitors. Materials scientist Pulickel Ajayan at Rice University created ribbons of vanadium oxide (VO2) thousands of times thinner than a sheet of paper, and combined those with atom-thick ribbons of graphene to form cathodes which were built …

Crushed, Rolled, or Slivered, Silicon Boosts Batteries

Dean Sigler Electric Powerplants, Sustainable Aviation Leave a Comment

Two different Rice University research teams are applying different but related approaches to using silicon in lithium batteries to make them more energy dense and longer-lived. One team recently came up with a paint-on lithium battery, announced a way to use otherwise waste silicon by crushing it and spreading it on anodes in their test batteries. This has implications for manufacturing because of the simplicity of the process. Dvice.com gives one hint as to why this might be good. “In lithium-ion batteries, for example, the anode is usually graphite, because it works well and is cheap. “You know what else is cheap? Silicon. The Earth is 28% silicon, making it the second most abundant crustal element by mass after oxygen. And it makes a fantastic battery anode, too: it can hold 10x more lithium ions than graphite. However, if you cram it full of all those ions, it swells in size [up to three times] and will damage itself, which …

Rice – That’s Nice, and Lights Up, Too

Dean Sigler Electric Powerplants, Sustainable Aviation Leave a Comment

Rice University announced the development of a spray-on (in this case airbrushed) coating that stores electricity, a bit reminiscent of Stanford’s paper battery on which a coating could be applied to act as a battery. Mitsubishi has demonstrated a paint that could act as an extremely thin-film solar cell, but Rice’s technology shows promise. Five layers comprise the various components of a lithium-ion battery and can seemingly be applied to almost any surface, including in one demonstration, a beer stein – showing an intoxicating range of possibilities. But Pulickel Ajayan, materials science professor has more serious considerations. According to the University’s news.  “This means traditional packaging for batteries has given way to a much more flexible approach that allows all kinds of new design and integration possibilities for storage devices,” said Ajayan, Rice’s Benjamin M. and Mary Greenwood Anderson Professor in Mechanical Engineering and Materials Science and of chemistry. “There has been lot of interest in recent times in creating …