The federal government is creating yet another round of incentives to “spark” development of “significantly smaller, lighter and less expensive batteries.” A consortium of researchers led by Pacific Northwest National Laboratory (PNNL) will receive up to $10 million a year over five years to perk up battery performance, with the goal of creating a 500 Watt-hour per kilogram battery pack, about three times that of currently available commercial offerings. The new batteries should be “reliable, safe and less expensive,” according to consortium director and PNNL materials scientist Jun Liu. Research will come from partners nation-wide, including: Brookhaven National Laboratory Idaho National Laboratory SLAC National Accelerator Laboratory Binghamton University (State University of New York) Stanford University University of California, San Diego University of Texas at Austin University of Washington IBM (advisory board member) Even though the goals and the budget seem similar to those explained by Energy Secretary Steven Chu two years ago, his directive included research on alternative materials, such …
Caging Silicon Anodes with Graphene
Dr. Yi Cui of Stanford University has expanded the idea of “battery” to include conductive ink on paper, fruit-like clusters of energy-storing capsules, and now, nano-sized graphene cages in which the energy can romp like a hamster in a plastic ball. He will be on hand at this year’s Sustainable Aviation Symposium on May 6, at the Sofitel San Francisco Bay hotel. His pioneering work with silicon as an electrode material goes back at least ten years, and has focused on overcoming silicon’s two major problems in battery use. Silicon expands and begins breaking down during repeated charge-discharge cycles. It reacts with battery electrolyte to form a coating that progressively destroys performance. The combination of crumbling and coating finally makes the battery inoperable. His group at Stanford had found a way to “wrap every silicon anode particle in a custom-fit cage made of graphene, a pure form of carbon that is the thinnest and strongest material known and a great conductor …
Milking Magnesium for All It’s Worth
Magnesium carries two positive charges for every one which lithium carries. This simple fact was inspiration for Jordi Cabana, a University of Illinois at Chicago assistant professor of chemistry in developing a magnesium-based battery. Using magnesium in place of lithium led to this thought: “Because magnesium is an ion that carries two positive charges, every time we introduce a magnesium ion in the structure of the battery material we can move twice as many electrons,” He added, “We hope that this work will open a credible design path for a new class of high-voltage, high-energy batteries.” Cabana and his associates have shown they can replace the lithium ions, each of which carries a single positive charge, with magnesium ions, which have a plus-two charge, in battery-like chemical reactions, using an electrode with a structure like those in many of today’s devices. According to the University, the research is part of the Joint Center for Energy Storage Research, a Department of …
Lighter, More Powerful, Cheaper. Can J-CESR Bring Us Better Batteries?
$70,000 is a sizable base price for a car. That sum for the simplest of Tesla S sedans makes a bigger than average debt load for most of us, probably more than most can responsibly assume. Even the much anticipated model “E” at half that price is more stunning than the average sticker shock these days. What if, by some act of art or science, that $70,000 could be slashed to $14,000 for an electric vehicle that could travel 265 miles on a charge? That tall order is the order of the day for the Joint Center for Energy Storage Research, started two years ago under Dr. Steven Chu, who was then U. S. Secretary of Energy. He and his “teams” were charged with establishing the cooperative enterprise at “Argonne National Laboratory with a budget of $120 million over five years to create a battery five times more powerful and five times cheaper than today’s norms – all within five …
Dr. Cui’s Pomegranate-inspired Battery Bears Fruit
Dr. Yi Cui seems to get inspiration from food. A few years ago, his research team came up with a “yolk-shell structure” that helped contain the high amount of lithium that silicon anodes were able to absorb. That battery design promised much, and an embellishment of that design seems to hold even greater promise. His newest effort, working at Stanford University with the Department of Energy’s SLAC National Accelerator Laboratory, features an electrode “designed like a pomegranate – with silicon nanoparticles clustered like seed in a tough carbon rind.” This approach, according to its inventors, overcomes several remaining obstacles to the use of silicon in a new generation of lithium-ion batteries. Yi said the battery’s efficiency and longevity are promising. “Experiments showed our pomegranate-inspired anode operates at 97 percent capacity even after 1,000 cycles of charging and discharging, which puts it well within the desired range for commercial operation.” Cui’s team has been working on preventing anode breakup for the …
I’ll Take Manhattan
While much of battery research goes into crafting the ultimate anode, cathode or electrolyte, there seem to be few efforts, at least to outside observers, of integrated approaches to making a better total battery. That may change soon, with the Department of Energy announcing formation of a new Joint Center for Energy Storage Research (J-CESR, or J-Caesar). Dr. Steven Chu, U. S. Secretary of Energy, has established the Center at Argonne National Laboratory with a budget of $120 million over five years to create a battery five times more powerful and five times cheaper than today’s norms – all within five years. For those of us who’ve grown wary of those “breakthough” announcements that almost always include the line, “researchers say the new product could become a commercial reality in the next five to 20 years,” this may seem too hopeful. Secretary Chu’s announcement included several factors that may alleviate this wariness. The Department is putting up the money, …