intercalation (countable and uncountable, plural intercalations) (chemistry) The reversible insertion of a molecule between two others. Wiktionary Enyuan Hu, a chemist at Brookhaven National Laboratory explains the importance, and limitations, of intercalation in battery chemistry. “The materials normally used in lithium-ion batteries are based on intercalation chemistry. This type of chemical reaction is very efficient; however, it only transfers a single electron, so the cathode capacity is limited. Some compounds like FeF3 are capable of transferring multiple electrons through a more complex reaction mechanism, called a conversion reaction.” Iron trifluoride (FeF3) is composed of “cost-effective and environmentally benign elements — iron and fluorine. Researchers have been interested in using chemical compounds like FeF3 in lithium-ion batteries because they offer inherently higher capacities than traditional cathode …
